High performance sorption and desorption behaviour

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As an adsorbent of gaseous ammonia, cobalt hexacyanocobaltate (CoII3[CoIII(CN)6]2) was proved to have good sorption even at high temperatures, with thermal recyclability in sorption–desorption cycles. The maximum sorption capacities evaluated with a dual-site Langmuir model are 25.2, 18.6, 8.6, and 2.1 mmol g−1 at 20, 100, 150, and 250 °C, respectively.

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